Stereoselective dihydroxylation reactions of γ-amino-α,β- unsaturated esters via their aryl ketimine derivatives

Joon Seok Oh; Jongho Jeon; Do Yeon Park; Young Gyu Kim

doi:10.1039/b414846k

Stereoselective dihydroxylation reactions of γ-amino-α,β- unsaturated esters via their aryl ketimine derivatives

Joon Seok Oh, Jongho Jeon, Do Yeon Park, Young Gyu Kim

Department of Applied Chemistry

Seoul National University

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

OsO₄-catalysed dihydroxylation reactions of the aryl ketimine derivatives of (E)-γ-amino-α,β-unsaturated esters gave anti selectivity ranging from 6.7:1 to 19:1, whereas the opposite syn selectivity was consistently observed with those of (Z)-γ-amino-α,β- unsaturated esters (5.4:1 to >100:1).

Original language	English
Pages (from-to)	770-771
Number of pages	2
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/b414846k
State	Published - 14 Feb 2005

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title = "Stereoselective dihydroxylation reactions of γ-amino-α,β- unsaturated esters via their aryl ketimine derivatives",

abstract = "OsO4-catalysed dihydroxylation reactions of the aryl ketimine derivatives of (E)-γ-amino-α,β-unsaturated esters gave anti selectivity ranging from 6.7:1 to 19:1, whereas the opposite syn selectivity was consistently observed with those of (Z)-γ-amino-α,β- unsaturated esters (5.4:1 to >100:1).",

author = "Oh, {Joon Seok} and Jongho Jeon and Park, {Do Yeon} and Kim, {Young Gyu}",

year = "2005",

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doi = "10.1039/b414846k",

language = "English",

pages = "770--771",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Stereoselective dihydroxylation reactions of γ-amino-α,β- unsaturated esters via their aryl ketimine derivatives

AU - Oh, Joon Seok

AU - Jeon, Jongho

AU - Park, Do Yeon

AU - Kim, Young Gyu

PY - 2005/2/14

Y1 - 2005/2/14

N2 - OsO4-catalysed dihydroxylation reactions of the aryl ketimine derivatives of (E)-γ-amino-α,β-unsaturated esters gave anti selectivity ranging from 6.7:1 to 19:1, whereas the opposite syn selectivity was consistently observed with those of (Z)-γ-amino-α,β- unsaturated esters (5.4:1 to >100:1).

AB - OsO4-catalysed dihydroxylation reactions of the aryl ketimine derivatives of (E)-γ-amino-α,β-unsaturated esters gave anti selectivity ranging from 6.7:1 to 19:1, whereas the opposite syn selectivity was consistently observed with those of (Z)-γ-amino-α,β- unsaturated esters (5.4:1 to >100:1).

UR - http://www.scopus.com/inward/record.url?scp=14644403006&partnerID=8YFLogxK

U2 - 10.1039/b414846k

DO - 10.1039/b414846k

M3 - Article

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AN - SCOPUS:14644403006

SN - 1359-7345

SP - 770

EP - 771

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Stereoselective dihydroxylation reactions of γ-amino-α,β- unsaturated esters via their aryl ketimine derivatives

Abstract

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