Steric control of the nuclearity of metallamacrocycles: Formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

Kyungjin Lee; Rohith P. John; Mira Park; Dohyun Moon; Hyeong Cheol Ri; Ghyung Hwa Kim; Myoung Soo Lah

doi:10.1039/b711686a

Steric control of the nuclearity of metallamacrocycles: Formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

Kyungjin Lee, Rohith P. John, Mira Park, Dohyun Moon, Hyeong Cheol Ri, Ghyung Hwa Kim, Myoung Soo Lah

Department of Physics

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

An S ₆-symmetric hexanuclear gallium metalladiazamacrocycle, [Ga^III₆L²₆ S ₆] with a –(ΛΔ)(ΛΔ)– chiral sequence and an S ₈-symmetric hexadecanuclear manganese metalladiazamacrocycle, [Mn^III₁₆L²₁₆ S ₁₆] with a –(ΛΛΔΔ)(ΛΛΔΔ)– chiral sequence were prepared using the same N ²-trans-cinnamoyl-2-hydroxy-3-naphthoylhydrazide (H₃L²) as a bridging pentadentate ligand between the metal centers for the formation of a macrocyclic system.

Original language	English
Pages (from-to)	131-136
Number of pages	6
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	1
DOIs	https://doi.org/10.1039/b711686a
State	Published - 16 Nov 2007

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title = "Steric control of the nuclearity of metallamacrocycles: Formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle",

abstract = "An S 6-symmetric hexanuclear gallium metalladiazamacrocycle, [GaIII6L26 S 6] with a –(ΛΔ)(ΛΔ)– chiral sequence and an S 8-symmetric hexadecanuclear manganese metalladiazamacrocycle, [MnIII16L216 S 16] with a –(ΛΛΔΔ)(ΛΛΔΔ)– chiral sequence were prepared using the same N 2-trans-cinnamoyl-2-hydroxy-3-naphthoylhydrazide (H3L2) as a bridging pentadentate ligand between the metal centers for the formation of a macrocyclic system.",

author = "Kyungjin Lee and John, {Rohith P.} and Mira Park and Dohyun Moon and Ri, {Hyeong Cheol} and Kim, {Ghyung Hwa} and Lah, {Myoung Soo}",

year = "2007",

month = nov,

day = "16",

doi = "10.1039/b711686a",

language = "English",

pages = "131--136",

journal = "Journal of the Chemical Society. Dalton Transactions",

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publisher = "Royal Society of Chemistry",

number = "1",

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Steric control of the nuclearity of metallamacrocycles: Formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle. / Lee, Kyungjin; John, Rohith P.; Park, Mira et al.
In: Journal of the Chemical Society. Dalton Transactions, No. 1, 16.11.2007, p. 131-136.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Steric control of the nuclearity of metallamacrocycles

T2 - Formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

AU - Lee, Kyungjin

AU - John, Rohith P.

AU - Park, Mira

AU - Moon, Dohyun

AU - Ri, Hyeong Cheol

AU - Kim, Ghyung Hwa

AU - Lah, Myoung Soo

PY - 2007/11/16

Y1 - 2007/11/16

N2 - An S 6-symmetric hexanuclear gallium metalladiazamacrocycle, [GaIII6L26 S 6] with a –(ΛΔ)(ΛΔ)– chiral sequence and an S 8-symmetric hexadecanuclear manganese metalladiazamacrocycle, [MnIII16L216 S 16] with a –(ΛΛΔΔ)(ΛΛΔΔ)– chiral sequence were prepared using the same N 2-trans-cinnamoyl-2-hydroxy-3-naphthoylhydrazide (H3L2) as a bridging pentadentate ligand between the metal centers for the formation of a macrocyclic system.

AB - An S 6-symmetric hexanuclear gallium metalladiazamacrocycle, [GaIII6L26 S 6] with a –(ΛΔ)(ΛΔ)– chiral sequence and an S 8-symmetric hexadecanuclear manganese metalladiazamacrocycle, [MnIII16L216 S 16] with a –(ΛΛΔΔ)(ΛΛΔΔ)– chiral sequence were prepared using the same N 2-trans-cinnamoyl-2-hydroxy-3-naphthoylhydrazide (H3L2) as a bridging pentadentate ligand between the metal centers for the formation of a macrocyclic system.

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DO - 10.1039/b711686a

M3 - Article

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SN - 1470-479X

SP - 131

EP - 136

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 1

ER -

Steric control of the nuclearity of metallamacrocycles: Formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

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