Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]3[Fe(CN)6]2·8H2O (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)

Min Ju Cha; Jong Won Shin; Young Hoon Lee; Yang Kim; Bong Gon Kim; Kil Sik Min

doi:10.1016/j.inoche.2009.04.018

Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]₃[Fe(CN)₆]₂·8H₂O (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)

Min Ju Cha, Jong Won Shin, Young Hoon Lee, Yang Kim, Bong Gon Kim, Kil Sik Min

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The one-dimensional coordination polymer like fern branch, [Cu^II(L)]₃[Fe^III(CN)₆]₂·8H₂O (1), which is linked by azamacrocyclic copper(II) complex and iron(III) hexacyanide, has been synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility measurement (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane). Compound 1 shows a weak ferromagnetic coupling between the copper(II) and low spin iron(III) ions in the one-dimensional chain structure.

Original language	English
Pages (from-to)	520-522
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2009.04.018
State	Published - Jun 2009

Keywords

Coordination polymer
Copper(II) complex
Crystal structure
Iron(III) hexacyanide
Magnetic properties

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10.1016/j.inoche.2009.04.018

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@article{d48a46640e1241659c165f329367c2b8,

title = "Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]3[Fe(CN)6]2·8H2O (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)",

abstract = "The one-dimensional coordination polymer like fern branch, [CuII(L)]3[FeIII(CN)6]2·8H2O (1), which is linked by azamacrocyclic copper(II) complex and iron(III) hexacyanide, has been synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility measurement (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane). Compound 1 shows a weak ferromagnetic coupling between the copper(II) and low spin iron(III) ions in the one-dimensional chain structure.",

keywords = "Coordination polymer, Copper(II) complex, Crystal structure, Iron(III) hexacyanide, Magnetic properties",

author = "Cha, {Min Ju} and Shin, {Jong Won} and Lee, {Young Hoon} and Yang Kim and Kim, {Bong Gon} and Min, {Kil Sik}",

year = "2009",

month = jun,

doi = "10.1016/j.inoche.2009.04.018",

language = "English",

volume = "12",

pages = "520--522",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

}

Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]₃[Fe(CN)₆]₂·8H₂O (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane). / Cha, Min Ju; Shin, Jong Won; Lee, Young Hoon et al.
In: Inorganic Chemistry Communications, Vol. 12, No. 6, 06.2009, p. 520-522.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]3[Fe(CN)6]2·8H2O (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)

AU - Cha, Min Ju

AU - Shin, Jong Won

AU - Lee, Young Hoon

AU - Kim, Yang

AU - Kim, Bong Gon

AU - Min, Kil Sik

PY - 2009/6

Y1 - 2009/6

N2 - The one-dimensional coordination polymer like fern branch, [CuII(L)]3[FeIII(CN)6]2·8H2O (1), which is linked by azamacrocyclic copper(II) complex and iron(III) hexacyanide, has been synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility measurement (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane). Compound 1 shows a weak ferromagnetic coupling between the copper(II) and low spin iron(III) ions in the one-dimensional chain structure.

AB - The one-dimensional coordination polymer like fern branch, [CuII(L)]3[FeIII(CN)6]2·8H2O (1), which is linked by azamacrocyclic copper(II) complex and iron(III) hexacyanide, has been synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility measurement (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane). Compound 1 shows a weak ferromagnetic coupling between the copper(II) and low spin iron(III) ions in the one-dimensional chain structure.

KW - Coordination polymer

KW - Copper(II) complex

KW - Crystal structure

KW - Iron(III) hexacyanide

KW - Magnetic properties

UR - http://www.scopus.com/inward/record.url?scp=67349221238&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2009.04.018

DO - 10.1016/j.inoche.2009.04.018

M3 - Article

AN - SCOPUS:67349221238

SN - 1387-7003

VL - 12

SP - 520

EP - 522

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Structure and magnetic properties of a novel branch-like one-dimensional cyano-bridged assembly [Cu(L)]₃[Fe(CN)₆]₂·8H₂O (L = 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)

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