TY - JOUR
T1 - Syntheses and Theoretical Study of Palladium(II) Complexes with Aminophosphines as 7-Membered Chelate Rings
AU - Kim, Bong Gon
AU - Yang, Kiyull
AU - Jung, Maeng Jun
AU - Lee, Bae Wook
AU - Doh, Myung Ki
PY - 1997
Y1 - 1997
N2 - Nature of palladium(II) complexes with 7-membered chelates was studied by experimental and theoretical methods on a Pd(L)Cl2 system, where L is Ph2PNHCH2CH2NHPPh2(L1), Ph2PNHC6,H4NHPPh2(L2). The palladium(II) complexes were prepared and characterized by elemental analysis, IR, UV, 1H, and 31P NMR spectroscopy. Ab initia calculations with geometry optimizations were also performed for related model systems, Pd(L)Cl2; L=R2PNH(CH2)2NHPR2(L3), R2PNHC6H4NHPR2(L4), R2P(CH2)4PR2(L5), R2PCH2(C6H4CH2- PR2 (L6); R=H, CH3.
AB - Nature of palladium(II) complexes with 7-membered chelates was studied by experimental and theoretical methods on a Pd(L)Cl2 system, where L is Ph2PNHCH2CH2NHPPh2(L1), Ph2PNHC6,H4NHPPh2(L2). The palladium(II) complexes were prepared and characterized by elemental analysis, IR, UV, 1H, and 31P NMR spectroscopy. Ab initia calculations with geometry optimizations were also performed for related model systems, Pd(L)Cl2; L=R2PNH(CH2)2NHPR2(L3), R2PNHC6H4NHPR2(L4), R2P(CH2)4PR2(L5), R2PCH2(C6H4CH2- PR2 (L6); R=H, CH3.
UR - http://www.scopus.com/inward/record.url?scp=0031351511&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0031351511
SN - 0253-2964
VL - 18
SP - 1162
EP - 1166
JO - Bulletin of the Korean Chemical Society
JF - Bulletin of the Korean Chemical Society
IS - 11
ER -