Syntheses and Theoretical Study of Palladium(II) Complexes with Aminophosphines as 7-Membered Chelate Rings

Bong Gon Kim; Kiyull Yang; Maeng Jun Jung; Bae Wook Lee; Myung Ki Doh

Syntheses and Theoretical Study of Palladium(II) Complexes with Aminophosphines as 7-Membered Chelate Rings

Bong Gon Kim
, Kiyull Yang
, Maeng Jun Jung
, Bae Wook Lee
, Myung Ki Doh

Gyeongsang National University
Yeungnam University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Nature of palladium(II) complexes with 7-membered chelates was studied by experimental and theoretical methods on a Pd(L)Cl₂ system, where L is Ph₂PNHCH₂CH₂NHPPh₂(L1), Ph₂PNHC₆,H₄NHPPh₂(L2). The palladium(II) complexes were prepared and characterized by elemental analysis, IR, UV, ¹H, and ³¹P NMR spectroscopy. Ab initia calculations with geometry optimizations were also performed for related model systems, Pd(L)Cl₂; L=R₂PNH(CH₂)₂NHPR₂(L3), R₂PNHC₆H₄NHPR₂(L4), R₂P(CH₂)₄PR₂(L5), R₂PCH₂(C₆H₄CH₂- PR₂ (L6); R=H, CH₃.

Original language	English
Pages (from-to)	1162-1166
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	18
Issue number	11
State	Published - 1997

Cite this

@article{b66cf396742e4487a98c7ccd5cde4f96,

title = "Syntheses and Theoretical Study of Palladium(II) Complexes with Aminophosphines as 7-Membered Chelate Rings",

abstract = "Nature of palladium(II) complexes with 7-membered chelates was studied by experimental and theoretical methods on a Pd(L)Cl2 system, where L is Ph2PNHCH2CH2NHPPh2(L1), Ph2PNHC6,H4NHPPh2(L2). The palladium(II) complexes were prepared and characterized by elemental analysis, IR, UV, 1H, and 31P NMR spectroscopy. Ab initia calculations with geometry optimizations were also performed for related model systems, Pd(L)Cl2; L=R2PNH(CH2)2NHPR2(L3), R2PNHC6H4NHPR2(L4), R2P(CH2)4PR2(L5), R2PCH2(C6H4CH2- PR2 (L6); R=H, CH3.",

author = "Kim, \{Bong Gon\} and Kiyull Yang and Jung, \{Maeng Jun\} and Lee, \{Bae Wook\} and Doh, \{Myung Ki\}",

year = "1997",

language = "English",

volume = "18",

pages = "1162--1166",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

publisher = "Wiley-Blackwell",

number = "11",

}

TY - JOUR

T1 - Syntheses and Theoretical Study of Palladium(II) Complexes with Aminophosphines as 7-Membered Chelate Rings

AU - Kim, Bong Gon

AU - Yang, Kiyull

AU - Jung, Maeng Jun

AU - Lee, Bae Wook

AU - Doh, Myung Ki

PY - 1997

Y1 - 1997

N2 - Nature of palladium(II) complexes with 7-membered chelates was studied by experimental and theoretical methods on a Pd(L)Cl2 system, where L is Ph2PNHCH2CH2NHPPh2(L1), Ph2PNHC6,H4NHPPh2(L2). The palladium(II) complexes were prepared and characterized by elemental analysis, IR, UV, 1H, and 31P NMR spectroscopy. Ab initia calculations with geometry optimizations were also performed for related model systems, Pd(L)Cl2; L=R2PNH(CH2)2NHPR2(L3), R2PNHC6H4NHPR2(L4), R2P(CH2)4PR2(L5), R2PCH2(C6H4CH2- PR2 (L6); R=H, CH3.

AB - Nature of palladium(II) complexes with 7-membered chelates was studied by experimental and theoretical methods on a Pd(L)Cl2 system, where L is Ph2PNHCH2CH2NHPPh2(L1), Ph2PNHC6,H4NHPPh2(L2). The palladium(II) complexes were prepared and characterized by elemental analysis, IR, UV, 1H, and 31P NMR spectroscopy. Ab initia calculations with geometry optimizations were also performed for related model systems, Pd(L)Cl2; L=R2PNH(CH2)2NHPR2(L3), R2PNHC6H4NHPR2(L4), R2P(CH2)4PR2(L5), R2PCH2(C6H4CH2- PR2 (L6); R=H, CH3.

UR - https://www.scopus.com/pages/publications/0031351511

M3 - Article

AN - SCOPUS:0031351511

SN - 0253-2964

VL - 18

SP - 1162

EP - 1166

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 11

ER -

Syntheses and Theoretical Study of Palladium(II) Complexes with Aminophosphines as 7-Membered Chelate Rings

Abstract

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