Synthesis and characterization of poly(pyrrole-co-aniline) copolymer using atmospheric pressure plasma polymerization

Eun Young Jung; Choon Sang Park; Hyo Jun Jang; Gyu Tae Bae; Bhum Jae Shin; Heung Sik Tae

doi:10.1080/15421406.2021.1972205

Synthesis and characterization of poly(pyrrole-co-aniline) copolymer using atmospheric pressure plasma polymerization

Eun Young Jung, Choon Sang Park, Hyo Jun Jang, Gyu Tae Bae, Bhum Jae Shin, Heung Sik Tae

School of Electronics Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

This paper investigates the characteristics of poly(pyrrole-co-aniline) copolymer (PYPAN) films deposited by using an atmospheric pressure plasma (APP) polymerization relative to various concentrations of aniline and pyrrole monomers. The surface morphology and structure properties of PYPAN films are observed to strongly depend on the pyrrole concentration (%), which is confirmed by Field emission-scanning electron microscopy (FE-SEM), Fourier transforms-infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and time of flight-secondary ion mass spectrometry (ToF-SIMS). In particular, it is observed that the PYPAN film grown at an optimal pyrrole concentration condition (that is, aniline 25% and pyrrole 75%) shows a lower electrical resistance and higher deposition rate.

Original language	English
Pages (from-to)	103-113
Number of pages	11
Journal	Molecular Crystals and Liquid Crystals
Volume	733
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2021.1972205
State	Published - 2022

Keywords

Aniline
atmospheric pressure plasma (APP) polymerization
conducting polymer
poly(pyrrole-co-aniline) copolymer
pyrrole

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10.1080/15421406.2021.1972205

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title = "Synthesis and characterization of poly(pyrrole-co-aniline) copolymer using atmospheric pressure plasma polymerization",

abstract = "This paper investigates the characteristics of poly(pyrrole-co-aniline) copolymer (PYPAN) films deposited by using an atmospheric pressure plasma (APP) polymerization relative to various concentrations of aniline and pyrrole monomers. The surface morphology and structure properties of PYPAN films are observed to strongly depend on the pyrrole concentration (%), which is confirmed by Field emission-scanning electron microscopy (FE-SEM), Fourier transforms-infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and time of flight-secondary ion mass spectrometry (ToF-SIMS). In particular, it is observed that the PYPAN film grown at an optimal pyrrole concentration condition (that is, aniline 25% and pyrrole 75%) shows a lower electrical resistance and higher deposition rate.",

keywords = "Aniline, atmospheric pressure plasma (APP) polymerization, conducting polymer, poly(pyrrole-co-aniline) copolymer, pyrrole",

author = "Jung, {Eun Young} and Park, {Choon Sang} and Jang, {Hyo Jun} and Bae, {Gyu Tae} and Shin, {Bhum Jae} and Tae, {Heung Sik}",

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year = "2022",

doi = "10.1080/15421406.2021.1972205",

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T1 - Synthesis and characterization of poly(pyrrole-co-aniline) copolymer using atmospheric pressure plasma polymerization

AU - Jung, Eun Young

AU - Park, Choon Sang

AU - Jang, Hyo Jun

AU - Bae, Gyu Tae

AU - Shin, Bhum Jae

AU - Tae, Heung Sik

PY - 2022

Y1 - 2022

N2 - This paper investigates the characteristics of poly(pyrrole-co-aniline) copolymer (PYPAN) films deposited by using an atmospheric pressure plasma (APP) polymerization relative to various concentrations of aniline and pyrrole monomers. The surface morphology and structure properties of PYPAN films are observed to strongly depend on the pyrrole concentration (%), which is confirmed by Field emission-scanning electron microscopy (FE-SEM), Fourier transforms-infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and time of flight-secondary ion mass spectrometry (ToF-SIMS). In particular, it is observed that the PYPAN film grown at an optimal pyrrole concentration condition (that is, aniline 25% and pyrrole 75%) shows a lower electrical resistance and higher deposition rate.

AB - This paper investigates the characteristics of poly(pyrrole-co-aniline) copolymer (PYPAN) films deposited by using an atmospheric pressure plasma (APP) polymerization relative to various concentrations of aniline and pyrrole monomers. The surface morphology and structure properties of PYPAN films are observed to strongly depend on the pyrrole concentration (%), which is confirmed by Field emission-scanning electron microscopy (FE-SEM), Fourier transforms-infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and time of flight-secondary ion mass spectrometry (ToF-SIMS). In particular, it is observed that the PYPAN film grown at an optimal pyrrole concentration condition (that is, aniline 25% and pyrrole 75%) shows a lower electrical resistance and higher deposition rate.

KW - Aniline

KW - atmospheric pressure plasma (APP) polymerization

KW - conducting polymer

KW - poly(pyrrole-co-aniline) copolymer

KW - pyrrole

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U2 - 10.1080/15421406.2021.1972205

DO - 10.1080/15421406.2021.1972205

M3 - Article

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SN - 1542-1406

VL - 733

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JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Synthesis and characterization of poly(pyrrole-co-aniline) copolymer using atmospheric pressure plasma polymerization

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Keywords

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