Synthesis and characterization of the vanadium-incorporated molecular sieve VAPO-5

Sung Hwa Jhung; Young Sun Uh; Hakze Chon

doi:10.1016/S0166-9834(00)82237-X

Synthesis and characterization of the vanadium-incorporated molecular sieve VAPO-5

Sung Hwa Jhung, Young Sun Uh, Hakze Chon

Korea Advanced Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

The vanadium-incorporated molecular sieve VAPO-5 was synthesized hydrothermally and characterized by X-ray diffraction, electron paramagnetic resonance, thermogravimetric analysis, diffuse reflectance spectroscopy, chemical analysis and adsorption techniques. It seems that the vanadium is incorporated mainly as V⁴⁺ in the as-synthesized VAPO-5 framework. The vanadium in VAPO-5 exists in a well dispersed state and shows redox properties, changing its oxidation state readily between V⁴⁺ and V⁵⁺.

Original language	English
Pages (from-to)	61-72
Number of pages	12
Journal	Applied Catalysis
Volume	62
Issue number	1
DOIs	https://doi.org/10.1016/S0166-9834(00)82237-X
State	Published - 1990

Keywords

catalyst characterization (XRD
catalyst preparation (crystallization)
DRS)
EPR
molecular sieves
TGA
vanadium-aluminophosphate
XPS

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10.1016/S0166-9834(00)82237-X

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title = "Synthesis and characterization of the vanadium-incorporated molecular sieve VAPO-5",

abstract = "The vanadium-incorporated molecular sieve VAPO-5 was synthesized hydrothermally and characterized by X-ray diffraction, electron paramagnetic resonance, thermogravimetric analysis, diffuse reflectance spectroscopy, chemical analysis and adsorption techniques. It seems that the vanadium is incorporated mainly as V4+ in the as-synthesized VAPO-5 framework. The vanadium in VAPO-5 exists in a well dispersed state and shows redox properties, changing its oxidation state readily between V4+ and V5+.",

keywords = "catalyst characterization (XRD, catalyst preparation (crystallization), DRS), EPR, molecular sieves, TGA, vanadium-aluminophosphate, XPS",

author = "Jhung, {Sung Hwa} and Uh, {Young Sun} and Hakze Chon",

year = "1990",

doi = "10.1016/S0166-9834(00)82237-X",

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T1 - Synthesis and characterization of the vanadium-incorporated molecular sieve VAPO-5

AU - Jhung, Sung Hwa

AU - Uh, Young Sun

AU - Chon, Hakze

PY - 1990

Y1 - 1990

N2 - The vanadium-incorporated molecular sieve VAPO-5 was synthesized hydrothermally and characterized by X-ray diffraction, electron paramagnetic resonance, thermogravimetric analysis, diffuse reflectance spectroscopy, chemical analysis and adsorption techniques. It seems that the vanadium is incorporated mainly as V4+ in the as-synthesized VAPO-5 framework. The vanadium in VAPO-5 exists in a well dispersed state and shows redox properties, changing its oxidation state readily between V4+ and V5+.

AB - The vanadium-incorporated molecular sieve VAPO-5 was synthesized hydrothermally and characterized by X-ray diffraction, electron paramagnetic resonance, thermogravimetric analysis, diffuse reflectance spectroscopy, chemical analysis and adsorption techniques. It seems that the vanadium is incorporated mainly as V4+ in the as-synthesized VAPO-5 framework. The vanadium in VAPO-5 exists in a well dispersed state and shows redox properties, changing its oxidation state readily between V4+ and V5+.

KW - catalyst characterization (XRD

KW - catalyst preparation (crystallization)

KW - DRS)

KW - EPR

KW - molecular sieves

KW - TGA

KW - vanadium-aluminophosphate

KW - XPS

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DO - 10.1016/S0166-9834(00)82237-X

M3 - Article

AN - SCOPUS:0025439850

SN - 0166-9834

VL - 62

SP - 61

EP - 72

JO - Applied Catalysis

JF - Applied Catalysis

IS - 1

ER -

Synthesis and characterization of the vanadium-incorporated molecular sieve VAPO-5

Abstract

Keywords

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