Synthesis of 2D metal-organic coordination polymers with large internal cavities and their magnetic properties

Hyunuk Kim, Minyoung Yoon, Gang Ho Lee, Dong Heon Lee, Joongpyo Shim, Kimoon Kim, Gyungse Park

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Two 2D metal-organic coordination polymers were synthesized through solvothermal reactions. The formation of 2D supramolecular networks was driven by intermolecular π-π stacking interactions between 2,2′-bipyridyl units of 1D coordination polymer chains. These 2D networks showed large cavities and windows for encapsulation of guest molecules. The networks showed weak antiferromagnetic exchange interactions at the low temperature.

Original languageEnglish
Pages (from-to)137-141
Number of pages5
JournalInorganic Chemistry Communications
Volume21
DOIs
StatePublished - Jul 2012

Keywords

  • π-π stacking interactions
  • Antiferromagnetic
  • Magnetic property
  • Metal-organic coordination polymer

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