Abstract
A comparative study on the Au(I)-catalyzed and IBr-promoted tandem cyclization of 1,5-enyne was reported. This study provides a meaningful mechanistic insight to the concerted nature of this tandem reaction and also provides interesting applications in the synthesis of 7/5- or 8/5-fused bicycles and biaryls.
Original language | English |
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Pages (from-to) | 670-677 |
Number of pages | 8 |
Journal | Bulletin of the Korean Chemical Society |
Volume | 31 |
Issue number | 3 |
DOIs | |
State | Published - Mar 2010 |
Keywords
- 1,5-enyne
- Carbocycles
- Gold catalysis
- Iodocyclization
- Tandem reaction