Abstract
A comparative study on the Au(I)-catalyzed and IBr-promoted tandem cyclization of 1,5-enyne was reported. This study provides a meaningful mechanistic insight to the concerted nature of this tandem reaction and also provides interesting applications in the synthesis of 7/5- or 8/5-fused bicycles and biaryls.
| Original language | English |
|---|---|
| Pages (from-to) | 670-677 |
| Number of pages | 8 |
| Journal | Bulletin of the Korean Chemical Society |
| Volume | 31 |
| Issue number | 3 |
| DOIs | |
| State | Published - Mar 2010 |
Keywords
- 1,5-enyne
- Carbocycles
- Gold catalysis
- Iodocyclization
- Tandem reaction
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