Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

Seung Uk Son; Kang Hyun Park; Young Shin Lee; Bo Yun Kim; Cheol Ho Choi; Myoung Soo Lan; Yun Hee Jang; Du Jeon Jang; Young Keun Chung

doi:10.1021/ic049514f

Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

Seung Uk Son, Kang Hyun Park, Young Shin Lee, Bo Yun Kim, Cheol Ho Choi, Myoung Soo Lan, Yun Hee Jang, Du Jeon Jang, Young Keun Chung

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164 Scopus citations

Abstract

Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)₃²⁺ and Ru(terpy)₂ ²⁺, respectively, were synthesized. The complex, which is analogous to Ru(terpy)₂²⁺, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.

Original language	English
Pages (from-to)	6896-6898
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	22
DOIs	https://doi.org/10.1021/ic049514f
State	Published - 1 Nov 2004

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title = "Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water",

abstract = "Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)32+ and Ru(terpy)2 2+, respectively, were synthesized. The complex, which is analogous to Ru(terpy)22+, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.",

author = "Son, {Seung Uk} and Park, {Kang Hyun} and Lee, {Young Shin} and Kim, {Bo Yun} and Choi, {Cheol Ho} and Lan, {Myoung Soo} and Jang, {Yun Hee} and Jang, {Du Jeon} and Chung, {Young Keun}",

year = "2004",

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journal = "Inorganic Chemistry",

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T1 - Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

AU - Son, Seung Uk

AU - Park, Kang Hyun

AU - Lee, Young Shin

AU - Kim, Bo Yun

AU - Choi, Cheol Ho

AU - Lan, Myoung Soo

AU - Jang, Yun Hee

AU - Jang, Du Jeon

AU - Chung, Young Keun

PY - 2004/11/1

Y1 - 2004/11/1

N2 - Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)32+ and Ru(terpy)2 2+, respectively, were synthesized. The complex, which is analogous to Ru(terpy)22+, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.

AB - Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)32+ and Ru(terpy)2 2+, respectively, were synthesized. The complex, which is analogous to Ru(terpy)22+, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.

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U2 - 10.1021/ic049514f

DO - 10.1021/ic049514f

M3 - Article

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EP - 6898

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

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