Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

Seung Uk Son; Kang Hyun Park; Young Shin Lee; Bo Yun Kim; Cheol Ho Choi; Myoung Soo Lan; Yun Hee Jang; Du Jeon Jang; Young Keun Chung

doi:10.1021/ic049514f

Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

Seung Uk Son
, Kang Hyun Park
, Young Shin Lee
, Bo Yun Kim
, Cheol Ho Choi
, Myoung Soo Lan
, Yun Hee Jang
, Du Jeon Jang
, Young Keun Chung

Seoul National University
Hanyang University

Research output: Contribution to journal › Article › peer-review

170 Scopus citations

Abstract

Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)₃²⁺ and Ru(terpy)₂ ²⁺, respectively, were synthesized. The complex, which is analogous to Ru(terpy)₂²⁺, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.

Original language	English
Pages (from-to)	6896-6898
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	22
DOIs	https://doi.org/10.1021/ic049514f
State	Published - 1 Nov 2004

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title = "Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water",

abstract = "Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)32+ and Ru(terpy)2 2+, respectively, were synthesized. The complex, which is analogous to Ru(terpy)22+, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.",

author = "Son, \{Seung Uk\} and Park, \{Kang Hyun\} and Lee, \{Young Shin\} and Kim, \{Bo Yun\} and Choi, \{Cheol Ho\} and Lan, \{Myoung Soo\} and Jang, \{Yun Hee\} and Jang, \{Du Jeon\} and Chung, \{Young Keun\}",

year = "2004",

month = nov,

day = "1",

doi = "10.1021/ic049514f",

language = "English",

volume = "43",

pages = "6896--6898",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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T1 - Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

AU - Son, Seung Uk

AU - Park, Kang Hyun

AU - Lee, Young Shin

AU - Kim, Bo Yun

AU - Choi, Cheol Ho

AU - Lan, Myoung Soo

AU - Jang, Yun Hee

AU - Jang, Du Jeon

AU - Chung, Young Keun

PY - 2004/11/1

Y1 - 2004/11/1

N2 - Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)32+ and Ru(terpy)2 2+, respectively, were synthesized. The complex, which is analogous to Ru(terpy)22+, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.

AB - Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)32+ and Ru(terpy)2 2+, respectively, were synthesized. The complex, which is analogous to Ru(terpy)22+, exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.

UR - https://www.scopus.com/pages/publications/7244256018

U2 - 10.1021/ic049514f

DO - 10.1021/ic049514f

M3 - Article

AN - SCOPUS:7244256018

SN - 0020-1669

VL - 43

SP - 6896

EP - 6898

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

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