Abstract
Step-shaped bismuth (Bi) nanowires were fabricated by direct current electrochemical deposition technique using diameter-modulated anodic aluminum oxide membranes (AAO) as templates. The nanowires have core-sheath structure with a crystalline rhombohedral Bi core surrounded by a mixed oxide (amorphous and monoclinic Bi2O3) layer. We observed transition of nanowire property from semimetal to semiconductor at wire diameter below 50 nm. Based on the semimetal to semiconductor transition property with just changing the wire diameter, the step-shaped Bi nanowires could be predicted to form a semimetal-semiconductor self-homojunction.
| Original language | English |
|---|---|
| Pages (from-to) | E21-E24 |
| Journal | Electrochemical and Solid-State Letters |
| Volume | 14 |
| Issue number | 6 |
| DOIs | |
| State | Published - 2011 |