Synthesis of submicron-sized rods and trees of Cu2O by radio-frequency magnetron sputtering

Vu Xuan Hien, Jae Lok You, Kwang Min Jo, Se Yun Kim, Joon Hyung Lee, Jeong Joo Kim, Young Woo Heo

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Typical sputtering conditions based on substrate temperature, sputtering time and oxygen partial pressure to grow thin film, submicron-sized rods and trees of Cu2O on glass substrates from metallic Cu targets were investigated. The submicron-rods with diameters of 100-700 nm and lengths of 2-8 μm were synthesized. The abundance of Cu species, which is modulated by the Ar/O2 ratio during the sputtering process affects directly to the growths of the Cu2O branches on the bodies of the submicronrods. Transmission electron microscopy and elemental mapping reveal that metallic Cu is existed on the heads of the Cu2O rods. Finally, the formation model of the submicron-sized rods and trees of Cu2O is discussed.

Original languageEnglish
Pages (from-to)60-67
Number of pages8
JournalVacuum
Volume111
DOIs
StatePublished - Jan 2015

Keywords

  • Crystal growth
  • Microstructure
  • Sputtering
  • Structural
  • Thick films

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