Synthesis of ZnO nanocrystals with cone, hexagonal cone, and rod shapes via non-hydrolytic ester elimination sol-gel reactions

Jin Joo; Soon G. Kwon; Jung H. Yu; Taeghwan Hyeon

doi:10.1002/adma.200402109

Synthesis of ZnO nanocrystals with cone, hexagonal cone, and rod shapes via non-hydrolytic ester elimination sol-gel reactions

Jin Joo
, Soon G. Kwon
, Jung H. Yu
, Taeghwan Hyeon

Department of Applied Chemistry

Seoul National University

Research output: Contribution to journal › Article › peer-review

271 Scopus citations

Abstract

The synthesis of novel wedge- and cone-shaped ZnO nanocrystals via a non-hydrolytic sol gel route based on the ester-elimination reaction between zinc aceteate and alcohol was carried out. ZnO nanocrystals with various shapes were synthesized using a variety of surfactants, including triotylphosphine oxide (TOPO), oleic acid (OA), 1-hexadexylamine (1-HDA), and tetradecylphosphonic acid (TDPA). Room temperature photoluminescence (PL) spectra of the ZnO nanocrystals were also shown. Studies revealed that an ester elimination reaction occurred between zinc acetate and 1,12-dodecanediol.

Original language	English
Pages (from-to)	1873-1877
Number of pages	5
Journal	Advanced Materials
Volume	17
Issue number	15
DOIs	https://doi.org/10.1002/adma.200402109
State	Published - 4 Aug 2005

Access to Document

10.1002/adma.200402109

Cite this

@article{6e5c740e420f40179fc0069e123691ea,

title = "Synthesis of ZnO nanocrystals with cone, hexagonal cone, and rod shapes via non-hydrolytic ester elimination sol-gel reactions",

abstract = "The synthesis of novel wedge- and cone-shaped ZnO nanocrystals via a non-hydrolytic sol gel route based on the ester-elimination reaction between zinc aceteate and alcohol was carried out. ZnO nanocrystals with various shapes were synthesized using a variety of surfactants, including triotylphosphine oxide (TOPO), oleic acid (OA), 1-hexadexylamine (1-HDA), and tetradecylphosphonic acid (TDPA). Room temperature photoluminescence (PL) spectra of the ZnO nanocrystals were also shown. Studies revealed that an ester elimination reaction occurred between zinc acetate and 1,12-dodecanediol.",

author = "Jin Joo and Kwon, \{Soon G.\} and Yu, \{Jung H.\} and Taeghwan Hyeon",

year = "2005",

month = aug,

day = "4",

doi = "10.1002/adma.200402109",

language = "English",

volume = "17",

pages = "1873--1877",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

number = "15",

}

TY - JOUR

T1 - Synthesis of ZnO nanocrystals with cone, hexagonal cone, and rod shapes via non-hydrolytic ester elimination sol-gel reactions

AU - Joo, Jin

AU - Kwon, Soon G.

AU - Yu, Jung H.

AU - Hyeon, Taeghwan

PY - 2005/8/4

Y1 - 2005/8/4

N2 - The synthesis of novel wedge- and cone-shaped ZnO nanocrystals via a non-hydrolytic sol gel route based on the ester-elimination reaction between zinc aceteate and alcohol was carried out. ZnO nanocrystals with various shapes were synthesized using a variety of surfactants, including triotylphosphine oxide (TOPO), oleic acid (OA), 1-hexadexylamine (1-HDA), and tetradecylphosphonic acid (TDPA). Room temperature photoluminescence (PL) spectra of the ZnO nanocrystals were also shown. Studies revealed that an ester elimination reaction occurred between zinc acetate and 1,12-dodecanediol.

AB - The synthesis of novel wedge- and cone-shaped ZnO nanocrystals via a non-hydrolytic sol gel route based on the ester-elimination reaction between zinc aceteate and alcohol was carried out. ZnO nanocrystals with various shapes were synthesized using a variety of surfactants, including triotylphosphine oxide (TOPO), oleic acid (OA), 1-hexadexylamine (1-HDA), and tetradecylphosphonic acid (TDPA). Room temperature photoluminescence (PL) spectra of the ZnO nanocrystals were also shown. Studies revealed that an ester elimination reaction occurred between zinc acetate and 1,12-dodecanediol.

UR - https://www.scopus.com/pages/publications/23744455468

U2 - 10.1002/adma.200402109

DO - 10.1002/adma.200402109

M3 - Article

AN - SCOPUS:23744455468

SN - 0935-9648

VL - 17

SP - 1873

EP - 1877

JO - Advanced Materials

JF - Advanced Materials

IS - 15

ER -

Synthesis of ZnO nanocrystals with cone, hexagonal cone, and rod shapes via non-hydrolytic ester elimination sol-gel reactions

Abstract

Access to Document

Other files and links

Fingerprint

Cite this