Synthesis, structure and magnetic properties of manganese(II) and cobalt(II) coordination polymers with bis(4-pyridyl)benzylamine

Su Young Kim; Ah Rim Jeong; Yuki Komatsumaru; Shinya Hayami; Kil Sik Min

doi:10.1007/s10847-019-00890-1

Synthesis, structure and magnetic properties of manganese(II) and cobalt(II) coordination polymers with bis(4-pyridyl)benzylamine

Su Young Kim, Ah Rim Jeong, Yuki Komatsumaru, Shinya Hayami, Kil Sik Min

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Coordination polymers [Mn₂(bpba)₃(NO₃)₄]_n·nCH₃CN·nCH₃CH₂OCH₂CH₃ (1) and [Co₂(bpba)₃(NO₃)₄]_n·nCH₃CN·nCH₃CH₂OCH₂CH₃ (2) were synthesized by the reaction of Mn(NO₃)₂·4H₂O or Co(NO₃)₂·6H₂O with bis(4-pyridyl)benzylamine (bpba) in CH₃CN/CH₃OH. The polymers were characterized by elemental analysis, spectroscopy, magnetic measurement, and single crystal X-ray diffraction. The manganese(II) ion of 1 was coordinated by three N atoms of three different bpba ligands and four O atoms of NO₃ ⁻ anions and displays a T-shaped geometry via bpba ligands. The extended structure of 1 shows a wave-like distorted brick wall configuration. The structure of 2 is isomorphous to that of 1. Polymers 1 and 2 showed weak antiferromagnetic interactions between the metal ions, respectively.

Original language	English
Pages (from-to)	167-174
Number of pages	8
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	94
Issue number	3-4
DOIs	https://doi.org/10.1007/s10847-019-00890-1
State	Published - 15 Aug 2019

Keywords

Cobalt(II)
Coordination polymer
Crystal structure
Manganese(II)
Molecular magnetism

Access to Document

10.1007/s10847-019-00890-1

Cite this

@article{898a058268344b79b3a72f095ba730c5,

title = "Synthesis, structure and magnetic properties of manganese(II) and cobalt(II) coordination polymers with bis(4-pyridyl)benzylamine",

abstract = "Coordination polymers [Mn2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (1) and [Co2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (2) were synthesized by the reaction of Mn(NO3)2·4H2O or Co(NO3)2·6H2O with bis(4-pyridyl)benzylamine (bpba) in CH3CN/CH3OH. The polymers were characterized by elemental analysis, spectroscopy, magnetic measurement, and single crystal X-ray diffraction. The manganese(II) ion of 1 was coordinated by three N atoms of three different bpba ligands and four O atoms of NO3 − anions and displays a T-shaped geometry via bpba ligands. The extended structure of 1 shows a wave-like distorted brick wall configuration. The structure of 2 is isomorphous to that of 1. Polymers 1 and 2 showed weak antiferromagnetic interactions between the metal ions, respectively.",

keywords = "Cobalt(II), Coordination polymer, Crystal structure, Manganese(II), Molecular magnetism",

author = "Kim, {Su Young} and Jeong, {Ah Rim} and Yuki Komatsumaru and Shinya Hayami and Min, {Kil Sik}",

note = "Publisher Copyright: {\textcopyright} 2019, Springer Nature B.V.",

year = "2019",

month = aug,

day = "15",

doi = "10.1007/s10847-019-00890-1",

language = "English",

volume = "94",

pages = "167--174",

journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

issn = "0923-0750",

publisher = "Springer",

number = "3-4",

}

TY - JOUR

T1 - Synthesis, structure and magnetic properties of manganese(II) and cobalt(II) coordination polymers with bis(4-pyridyl)benzylamine

AU - Kim, Su Young

AU - Jeong, Ah Rim

AU - Komatsumaru, Yuki

AU - Hayami, Shinya

AU - Min, Kil Sik

PY - 2019/8/15

Y1 - 2019/8/15

N2 - Coordination polymers [Mn2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (1) and [Co2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (2) were synthesized by the reaction of Mn(NO3)2·4H2O or Co(NO3)2·6H2O with bis(4-pyridyl)benzylamine (bpba) in CH3CN/CH3OH. The polymers were characterized by elemental analysis, spectroscopy, magnetic measurement, and single crystal X-ray diffraction. The manganese(II) ion of 1 was coordinated by three N atoms of three different bpba ligands and four O atoms of NO3 − anions and displays a T-shaped geometry via bpba ligands. The extended structure of 1 shows a wave-like distorted brick wall configuration. The structure of 2 is isomorphous to that of 1. Polymers 1 and 2 showed weak antiferromagnetic interactions between the metal ions, respectively.

AB - Coordination polymers [Mn2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (1) and [Co2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (2) were synthesized by the reaction of Mn(NO3)2·4H2O or Co(NO3)2·6H2O with bis(4-pyridyl)benzylamine (bpba) in CH3CN/CH3OH. The polymers were characterized by elemental analysis, spectroscopy, magnetic measurement, and single crystal X-ray diffraction. The manganese(II) ion of 1 was coordinated by three N atoms of three different bpba ligands and four O atoms of NO3 − anions and displays a T-shaped geometry via bpba ligands. The extended structure of 1 shows a wave-like distorted brick wall configuration. The structure of 2 is isomorphous to that of 1. Polymers 1 and 2 showed weak antiferromagnetic interactions between the metal ions, respectively.

KW - Cobalt(II)

KW - Coordination polymer

KW - Crystal structure

KW - Manganese(II)

KW - Molecular magnetism

UR - http://www.scopus.com/inward/record.url?scp=85068739576&partnerID=8YFLogxK

U2 - 10.1007/s10847-019-00890-1

DO - 10.1007/s10847-019-00890-1

M3 - Article

AN - SCOPUS:85068739576

SN - 0923-0750

VL - 94

SP - 167

EP - 174

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 3-4

ER -

Synthesis, structure and magnetic properties of manganese(II) and cobalt(II) coordination polymers with bis(4-pyridyl)benzylamine

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this