Synthesis, structure and photoluminescence properties of silver(I) coordination polymers with bis(4-pyridyl)benzylamine

Jong Won Shin; Hyun Jung Cho; Kil Sik Min

doi:10.1016/j.inoche.2011.11.016

Synthesis, structure and photoluminescence properties of silver(I) coordination polymers with bis(4-pyridyl)benzylamine

Jong Won Shin, Hyun Jung Cho, Kil Sik Min

Department of Chemical Science Education

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Silver(I) coordination polymers, [Ag(bpba)(CF ₃SO ₃)]•0.5CH ₃CN (1) and [Ag ₂(bpba) ₂(NO ₃) ₂]•CH ₃CN•H ₂O (2) with bis(4-pyridyl)benzylamine (bpba) have been prepared and structurally characterized. 1 shows two-dimensional structure formed by the offset π-π stacking interactions between ladder-like chains, whereas 2 displays three-dimensional network linked by one-dimensional chains with 8-shaped. Different from 1, 2 appears a strong visible emission ranging from 450 to 550 nm.

Original language	English
Pages (from-to)	12-16
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	16
DOIs	https://doi.org/10.1016/j.inoche.2011.11.016
State	Published - Feb 2012

Keywords

Coordination polymer
Crystal structure
Ligand
Photoluminescence
Silver(I) compound

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10.1016/j.inoche.2011.11.016

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title = "Synthesis, structure and photoluminescence properties of silver(I) coordination polymers with bis(4-pyridyl)benzylamine",

abstract = "Silver(I) coordination polymers, [Ag(bpba)(CF 3SO 3)]•0.5CH 3CN (1) and [Ag 2(bpba) 2(NO 3) 2]•CH 3CN•H 2O (2) with bis(4-pyridyl)benzylamine (bpba) have been prepared and structurally characterized. 1 shows two-dimensional structure formed by the offset π-π stacking interactions between ladder-like chains, whereas 2 displays three-dimensional network linked by one-dimensional chains with 8-shaped. Different from 1, 2 appears a strong visible emission ranging from 450 to 550 nm.",

keywords = "Coordination polymer, Crystal structure, Ligand, Photoluminescence, Silver(I) compound",

author = "Shin, {Jong Won} and Cho, {Hyun Jung} and Min, {Kil Sik}",

year = "2012",

month = feb,

doi = "10.1016/j.inoche.2011.11.016",

language = "English",

volume = "16",

pages = "12--16",

journal = "Inorganic Chemistry Communications",

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T1 - Synthesis, structure and photoluminescence properties of silver(I) coordination polymers with bis(4-pyridyl)benzylamine

AU - Shin, Jong Won

AU - Cho, Hyun Jung

AU - Min, Kil Sik

PY - 2012/2

Y1 - 2012/2

N2 - Silver(I) coordination polymers, [Ag(bpba)(CF 3SO 3)]•0.5CH 3CN (1) and [Ag 2(bpba) 2(NO 3) 2]•CH 3CN•H 2O (2) with bis(4-pyridyl)benzylamine (bpba) have been prepared and structurally characterized. 1 shows two-dimensional structure formed by the offset π-π stacking interactions between ladder-like chains, whereas 2 displays three-dimensional network linked by one-dimensional chains with 8-shaped. Different from 1, 2 appears a strong visible emission ranging from 450 to 550 nm.

AB - Silver(I) coordination polymers, [Ag(bpba)(CF 3SO 3)]•0.5CH 3CN (1) and [Ag 2(bpba) 2(NO 3) 2]•CH 3CN•H 2O (2) with bis(4-pyridyl)benzylamine (bpba) have been prepared and structurally characterized. 1 shows two-dimensional structure formed by the offset π-π stacking interactions between ladder-like chains, whereas 2 displays three-dimensional network linked by one-dimensional chains with 8-shaped. Different from 1, 2 appears a strong visible emission ranging from 450 to 550 nm.

KW - Coordination polymer

KW - Crystal structure

KW - Ligand

KW - Photoluminescence

KW - Silver(I) compound

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DO - 10.1016/j.inoche.2011.11.016

M3 - Article

AN - SCOPUS:84855661117

SN - 1387-7003

VL - 16

SP - 12

EP - 16

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis, structure and photoluminescence properties of silver(I) coordination polymers with bis(4-pyridyl)benzylamine

Abstract

Keywords

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