Temperature-triggered gate opening for gas adsorption in microporous manganese formate

  • Hyunuk Kim
  • , Denis G. Samsonenko
  • , Minyoung Yoon
  • , Ji Woong Yoon
  • , Young Kyu Hwang
  • , Jong San Chang
  • , Kimoon Kim

Research output: Contribution to journalArticlepeer-review

74 Scopus citations

Abstract

Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature.

Original languageEnglish
Pages (from-to)4697-4699
Number of pages3
JournalChemical Communications
Issue number39
DOIs
StatePublished - 2008

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