Tetra-μ-benzoato-bis-[(3-methyl-quinoline)copper(II)](Cu - Cu)

Byeong Kwon Park, Kyung Hwan Jang, Pan Gi Kim, Cheal Kim, Youngmee Kim

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9 Scopus citations

Abstract

In the title compound, [Cu2(C7H5O2)4(C10H9N)2], the paddle-wheel-type dinuclear complex mol-ecule contains four bridging benzoate groups and two terminal 3-methyl-quinoline ligands. The asymmetric unit contains one and a half mol-ecules with a total of three independent Cu atoms; there is an inversion center at the mid-point of the Cu⋯Cu bond in one molecule. The octa-hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a 3-methyl-quinoline ligand [Cu - N = 2.190 (4)-2.203 (3) Å] and by another Cu atom [Cu⋯Cu = 2.667 (1) and 2.6703 (7) Å]. The Cu atoms are all ca 0.22 Å out of the plane of the four bonded O atoms.

Original languageEnglish
Pages (from-to)m1141
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number9
DOIs
StatePublished - 2008

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