The first example of carbonylation of triarylbismuthines: Remarkable rhodium(I) catalysis

Chan Sik Cho; Toshiyuki Ohe; Osamu Itoh; Sakae Uemura

doi:10.1039/C39920000453

The first example of carbonylation of triarylbismuthines: Remarkable rhodium(I) catalysis

Chan Sik Cho, Toshiyuki Ohe, Osamu Itoh, Sakae Uemura

Department of Applied Chemistry

Kyoto University

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Triarylbismuthines (Ar₃Bi: Ar = C₆H₅, 4-MeC₆H₄, 4-MeOC₆H₄, 4-ClC ₆H₄) react with atmospheric pressure of carbon monoxide in acetonitrile, tetrahydrofuran or methanol at 25°C in the presence of a catalytic amount of either [RhCl(CO)₂]₂ or RhCl ₃·3H₂O to produce the corresponding diaryl ketones in good yields, methyl benzoates being also formed in methanol.

Original language	English
Pages (from-to)	453-454
Number of pages	2
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39920000453
State	Published - 1992

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title = "The first example of carbonylation of triarylbismuthines: Remarkable rhodium(I) catalysis",

abstract = "Triarylbismuthines (Ar3Bi: Ar = C6H5, 4-MeC6H4, 4-MeOC6H4, 4-ClC 6H4) react with atmospheric pressure of carbon monoxide in acetonitrile, tetrahydrofuran or methanol at 25°C in the presence of a catalytic amount of either [RhCl(CO)2]2 or RhCl 3·3H2O to produce the corresponding diaryl ketones in good yields, methyl benzoates being also formed in methanol.",

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year = "1992",

doi = "10.1039/C39920000453",

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journal = "Chemical Communications",

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T2 - Remarkable rhodium(I) catalysis

AU - Cho, Chan Sik

AU - Ohe, Toshiyuki

AU - Itoh, Osamu

AU - Uemura, Sakae

PY - 1992

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N2 - Triarylbismuthines (Ar3Bi: Ar = C6H5, 4-MeC6H4, 4-MeOC6H4, 4-ClC 6H4) react with atmospheric pressure of carbon monoxide in acetonitrile, tetrahydrofuran or methanol at 25°C in the presence of a catalytic amount of either [RhCl(CO)2]2 or RhCl 3·3H2O to produce the corresponding diaryl ketones in good yields, methyl benzoates being also formed in methanol.

AB - Triarylbismuthines (Ar3Bi: Ar = C6H5, 4-MeC6H4, 4-MeOC6H4, 4-ClC 6H4) react with atmospheric pressure of carbon monoxide in acetonitrile, tetrahydrofuran or methanol at 25°C in the presence of a catalytic amount of either [RhCl(CO)2]2 or RhCl 3·3H2O to produce the corresponding diaryl ketones in good yields, methyl benzoates being also formed in methanol.

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ER -

The first example of carbonylation of triarylbismuthines: Remarkable rhodium(I) catalysis

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