Abstract
Diamond-like carbon (DLC) films were produced by r.f. discharge decomposition of methane gas on an r.f.-powered, negatively self-biased electrode. The electrical, optical and mechanical properties of the films are found to be strongly dependent on the deposition conditions. Negative self-bias voltage and gas pressure are shown to be the two most important deposition parameters for accurate control over the properties of DLC films. The electrical resistivity, optical transparency, optical band gap and hardness were examined as functions of the r.f. power and gas pressure. Also, the crystallographic structure was examined by transmission electron microscopy and diamond microcrystals were observed in DLC films. An insulating, transparent, very hard film containing diamond microcrystals could be obtained under optimal conditions from the decomposition of CH4 gas by a 13.56 MHz r.f. discharge.
Original language | English |
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Pages (from-to) | 49-58 |
Number of pages | 10 |
Journal | Thin Solid Films |
Volume | 204 |
Issue number | 1 |
DOIs | |
State | Published - 20 Sep 1991 |