Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce möbius aromatic molecules

Mitsunori Inoue; Kil Suk Kim; Masaaki Suzuki; Jong Min Lim; Jae Yoon Shin; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.200902677

Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce möbius aromatic molecules

Mitsunori Inoue, Kil Suk Kim, Masaaki Suzuki, Jong Min Lim, Jae Yoon Shin, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Fuse to twist: Simple thermal reactions of meso-(3-thienyl) groups in Hückel-aromatic [26]hexaphyrins (see picture, left; N blue, S yellow, F green) provide 3-thienyl-fused [28] hexaphyrins (right) that have Möbius aromatic character, as indicated by a number of spectroscopic methods.

Original language	English
Pages (from-to)	6687-6690
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	36
DOIs	https://doi.org/10.1002/anie.200902677
State	Published - 24 Aug 2009

Keywords

Aromatlcity
Electronic structure
Hexaphyrins
Möbius aromaticity
Porphyrinoids

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10.1002/anie.200902677

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AU - Inoue, Mitsunori

AU - Kim, Kil Suk

AU - Suzuki, Masaaki

AU - Lim, Jong Min

AU - Shin, Jae Yoon

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2009/8/24

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N2 - Fuse to twist: Simple thermal reactions of meso-(3-thienyl) groups in Hückel-aromatic [26]hexaphyrins (see picture, left; N blue, S yellow, F green) provide 3-thienyl-fused [28] hexaphyrins (right) that have Möbius aromatic character, as indicated by a number of spectroscopic methods.

AB - Fuse to twist: Simple thermal reactions of meso-(3-thienyl) groups in Hückel-aromatic [26]hexaphyrins (see picture, left; N blue, S yellow, F green) provide 3-thienyl-fused [28] hexaphyrins (right) that have Möbius aromatic character, as indicated by a number of spectroscopic methods.

KW - Aromatlcity

KW - Electronic structure

KW - Hexaphyrins

KW - Möbius aromaticity

KW - Porphyrinoids

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ER -

Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce möbius aromatic molecules

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Keywords

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