Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce möbius aromatic molecules

Mitsunori Inoue; Kil Suk Kim; Masaaki Suzuki; Jong Min Lim; Jae Yoon Shin; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.200902677

Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce möbius aromatic molecules

Mitsunori Inoue
, Kil Suk Kim
, Masaaki Suzuki
, Jong Min Lim
, Jae Yoon Shin
, Dongho Kim
, Atsuhiro Osuka

Kyoto University
Yonsei University

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Fuse to twist: Simple thermal reactions of meso-(3-thienyl) groups in Hückel-aromatic [26]hexaphyrins (see picture, left; N blue, S yellow, F green) provide 3-thienyl-fused [28] hexaphyrins (right) that have Möbius aromatic character, as indicated by a number of spectroscopic methods.

Original language	English
Pages (from-to)	6687-6690
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	36
DOIs	https://doi.org/10.1002/anie.200902677
State	Published - 24 Aug 2009

Keywords

Aromatlcity
Electronic structure
Hexaphyrins
Möbius aromaticity
Porphyrinoids

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10.1002/anie.200902677

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title = "Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce m{\"o}bius aromatic molecules",

abstract = "Fuse to twist: Simple thermal reactions of meso-(3-thienyl) groups in H{\"u}ckel-aromatic [26]hexaphyrins (see picture, left; N blue, S yellow, F green) provide 3-thienyl-fused [28] hexaphyrins (right) that have M{\"o}bius aromatic character, as indicated by a number of spectroscopic methods.",

keywords = "Aromatlcity, Electronic structure, Hexaphyrins, M{\"o}bius aromaticity, Porphyrinoids",

author = "Mitsunori Inoue and Kim, \{Kil Suk\} and Masaaki Suzuki and Lim, \{Jong Min\} and Shin, \{Jae Yoon\} and Dongho Kim and Atsuhiro Osuka",

year = "2009",

month = aug,

day = "24",

doi = "10.1002/anie.200902677",

language = "English",

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T1 - Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce möbius aromatic molecules

AU - Inoue, Mitsunori

AU - Kim, Kil Suk

AU - Suzuki, Masaaki

AU - Lim, Jong Min

AU - Shin, Jae Yoon

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2009/8/24

Y1 - 2009/8/24

N2 - Fuse to twist: Simple thermal reactions of meso-(3-thienyl) groups in Hückel-aromatic [26]hexaphyrins (see picture, left; N blue, S yellow, F green) provide 3-thienyl-fused [28] hexaphyrins (right) that have Möbius aromatic character, as indicated by a number of spectroscopic methods.

AB - Fuse to twist: Simple thermal reactions of meso-(3-thienyl) groups in Hückel-aromatic [26]hexaphyrins (see picture, left; N blue, S yellow, F green) provide 3-thienyl-fused [28] hexaphyrins (right) that have Möbius aromatic character, as indicated by a number of spectroscopic methods.

KW - Aromatlcity

KW - Electronic structure

KW - Hexaphyrins

KW - Möbius aromaticity

KW - Porphyrinoids

UR - https://www.scopus.com/pages/publications/70349929716

U2 - 10.1002/anie.200902677

DO - 10.1002/anie.200902677

M3 - Article

AN - SCOPUS:70349929716

SN - 1433-7851

VL - 48

SP - 6687

EP - 6690

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Thermal fusion reactions of meso-(3-thienyl) groups in [26]hexaphyrins to produce möbius aromatic molecules

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Keywords

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