Three component controls in pillared metal-organic frameworks for catalytic carbon dioxide fixation

Jinmi Noh; Dasom Kim; Jihyun Lee; Minyoung Yoon; Myung Hwan Park; Kang Mun Lee; Youngjo Kim; Min Kim

doi:10.3390/catal8110565

Three component controls in pillared metal-organic frameworks for catalytic carbon dioxide fixation

Jinmi Noh, Dasom Kim, Jihyun Lee, Minyoung Yoon, Myung Hwan Park, Kang Mun Lee, Youngjo Kim, Min Kim

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Three components of pillared metal-organic frameworks (MOFs, three components = metal ion, carboxylic acid ligand, and N-chelating ligand) were controlled for CO₂ cycloaddition catalysts to synthesize organic cyclic carbonates. Among the divalent metals, Zn²⁺ showed the best catalytic activity, and in DABCO (1,4-diazabicyclo[2.2.2]octane)-based MOFs, hydroxy-functionalized DMOF-OH was the most efficient MOF for CO₂ cycloaddition. For the BPY (4,4’-bipyridyl)-type MOFs, all five prepared BMOFs (BPY MOFs) showed similar and good conversions for CO₂ cycloaddition. Finally, this pillared MOF could be recycled up to three times without activity and crystallinity loss.

Original language	English
Article number	565
Journal	Catalysts
Volume	8
Issue number	11
DOIs	https://doi.org/10.3390/catal8110565
State	Published - 20 Nov 2018

Keywords

Carbon dioxide
Catalysis
Coordination polymer
Cycloaddition
Metal-organic framework

Access to Document

10.3390/catal8110565

Cite this

@article{8f6795364ce0468ba81abe4f284e288c,

title = "Three component controls in pillared metal-organic frameworks for catalytic carbon dioxide fixation",

abstract = "Three components of pillared metal-organic frameworks (MOFs, three components = metal ion, carboxylic acid ligand, and N-chelating ligand) were controlled for CO2 cycloaddition catalysts to synthesize organic cyclic carbonates. Among the divalent metals, Zn2+ showed the best catalytic activity, and in DABCO (1,4-diazabicyclo[2.2.2]octane)-based MOFs, hydroxy-functionalized DMOF-OH was the most efficient MOF for CO2 cycloaddition. For the BPY (4,4{\textquoteright}-bipyridyl)-type MOFs, all five prepared BMOFs (BPY MOFs) showed similar and good conversions for CO2 cycloaddition. Finally, this pillared MOF could be recycled up to three times without activity and crystallinity loss.",

keywords = "Carbon dioxide, Catalysis, Coordination polymer, Cycloaddition, Metal-organic framework",

author = "Jinmi Noh and Dasom Kim and Jihyun Lee and Minyoung Yoon and Park, {Myung Hwan} and Lee, {Kang Mun} and Youngjo Kim and Min Kim",

note = "Publisher Copyright: {\textcopyright} 2018 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2018",

month = nov,

day = "20",

doi = "10.3390/catal8110565",

language = "English",

volume = "8",

journal = "Catalysts",

issn = "2073-4344",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "11",

}

TY - JOUR

T1 - Three component controls in pillared metal-organic frameworks for catalytic carbon dioxide fixation

AU - Noh, Jinmi

AU - Kim, Dasom

AU - Lee, Jihyun

AU - Yoon, Minyoung

AU - Park, Myung Hwan

AU - Lee, Kang Mun

AU - Kim, Youngjo

AU - Kim, Min

PY - 2018/11/20

Y1 - 2018/11/20

N2 - Three components of pillared metal-organic frameworks (MOFs, three components = metal ion, carboxylic acid ligand, and N-chelating ligand) were controlled for CO2 cycloaddition catalysts to synthesize organic cyclic carbonates. Among the divalent metals, Zn2+ showed the best catalytic activity, and in DABCO (1,4-diazabicyclo[2.2.2]octane)-based MOFs, hydroxy-functionalized DMOF-OH was the most efficient MOF for CO2 cycloaddition. For the BPY (4,4’-bipyridyl)-type MOFs, all five prepared BMOFs (BPY MOFs) showed similar and good conversions for CO2 cycloaddition. Finally, this pillared MOF could be recycled up to three times without activity and crystallinity loss.

AB - Three components of pillared metal-organic frameworks (MOFs, three components = metal ion, carboxylic acid ligand, and N-chelating ligand) were controlled for CO2 cycloaddition catalysts to synthesize organic cyclic carbonates. Among the divalent metals, Zn2+ showed the best catalytic activity, and in DABCO (1,4-diazabicyclo[2.2.2]octane)-based MOFs, hydroxy-functionalized DMOF-OH was the most efficient MOF for CO2 cycloaddition. For the BPY (4,4’-bipyridyl)-type MOFs, all five prepared BMOFs (BPY MOFs) showed similar and good conversions for CO2 cycloaddition. Finally, this pillared MOF could be recycled up to three times without activity and crystallinity loss.

KW - Carbon dioxide

KW - Catalysis

KW - Coordination polymer

KW - Cycloaddition

KW - Metal-organic framework

UR - http://www.scopus.com/inward/record.url?scp=85057246287&partnerID=8YFLogxK

U2 - 10.3390/catal8110565

DO - 10.3390/catal8110565

M3 - Article

AN - SCOPUS:85057246287

SN - 2073-4344

VL - 8

JO - Catalysts

JF - Catalysts

IS - 11

M1 - 565

ER -

Three component controls in pillared metal-organic frameworks for catalytic carbon dioxide fixation

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this