Three-dimensional cage type mesoporous CN-based hybrid material with very high surface area and pore volume

Ajayan Vinu; Pavuluri Srinivasu; Dhanashri P. Sawant; Toshiyuki Mori; Katsuhiko Ariga; Jong San Chang; Sung Hwa Jhung; Veerappan Vaithilingam Balasubramanian; Young Kyu Hwang

doi:10.1021/cm070657k

Three-dimensional cage type mesoporous CN-based hybrid material with very high surface area and pore volume

Ajayan Vinu
, Pavuluri Srinivasu
, Dhanashri P. Sawant
, Toshiyuki Mori
, Katsuhiko Ariga
, Jong San Chang
, Sung Hwa Jhung
, Veerappan Vaithilingam Balasubramanian
, Young Kyu Hwang

National Institute for Materials Science Tsukuba
Korea Research Institute of Chemical Technology

Research output: Contribution to journal › Article › peer-review

136 Scopus citations

Abstract

A novel highly ordered three-dimensional mesoporous carbon-nitride-based hybrid material (MCN-2) with very high surface area, pore volume, and a possible cage type porous structure has been prepared using three-dimensional cage type mesoporous silica, SBA-16, as a template through a simple polymerization reaction between ethylenediamine and carbon tetrachloride. The material has been unambiguously characterized by various sophisticated techniques such as XRD, nitrogen adsorption, HRTEM, EELS, XPS, 13C DD-MAS, and FT-IR spectroscopy. The XD result reveals that MCN-2 possesses three-dimensional structure with a possible Im3m space group. The specific surface area and pore volume of MCN-2 are significantly higher as compared to those of the template and MCN-I. Because of the excellent textural characteristic and three-dimensional porous structure, we believe that the MCN-2 could offer great potential for the applications such as catalysis and adsorption.

Original language	English
Pages (from-to)	4367-4372
Number of pages	6
Journal	Chemistry of Materials
Volume	19
Issue number	17
DOIs	https://doi.org/10.1021/cm070657k
State	Published - 21 Aug 2007

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@article{5884656b4d6c4281b3670914fa5a366d,

title = "Three-dimensional cage type mesoporous CN-based hybrid material with very high surface area and pore volume",

abstract = "A novel highly ordered three-dimensional mesoporous carbon-nitride-based hybrid material (MCN-2) with very high surface area, pore volume, and a possible cage type porous structure has been prepared using three-dimensional cage type mesoporous silica, SBA-16, as a template through a simple polymerization reaction between ethylenediamine and carbon tetrachloride. The material has been unambiguously characterized by various sophisticated techniques such as XRD, nitrogen adsorption, HRTEM, EELS, XPS, 13C DD-MAS, and FT-IR spectroscopy. The XD result reveals that MCN-2 possesses three-dimensional structure with a possible Im3m space group. The specific surface area and pore volume of MCN-2 are significantly higher as compared to those of the template and MCN-I. Because of the excellent textural characteristic and three-dimensional porous structure, we believe that the MCN-2 could offer great potential for the applications such as catalysis and adsorption.",

author = "Ajayan Vinu and Pavuluri Srinivasu and Sawant, \{Dhanashri P.\} and Toshiyuki Mori and Katsuhiko Ariga and Chang, \{Jong San\} and Jhung, \{Sung Hwa\} and Balasubramanian, \{Veerappan Vaithilingam\} and Hwang, \{Young Kyu\}",

year = "2007",

month = aug,

day = "21",

doi = "10.1021/cm070657k",

language = "English",

volume = "19",

pages = "4367--4372",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "17",

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TY - JOUR

T1 - Three-dimensional cage type mesoporous CN-based hybrid material with very high surface area and pore volume

AU - Vinu, Ajayan

AU - Srinivasu, Pavuluri

AU - Sawant, Dhanashri P.

AU - Mori, Toshiyuki

AU - Ariga, Katsuhiko

AU - Chang, Jong San

AU - Jhung, Sung Hwa

AU - Balasubramanian, Veerappan Vaithilingam

AU - Hwang, Young Kyu

PY - 2007/8/21

Y1 - 2007/8/21

N2 - A novel highly ordered three-dimensional mesoporous carbon-nitride-based hybrid material (MCN-2) with very high surface area, pore volume, and a possible cage type porous structure has been prepared using three-dimensional cage type mesoporous silica, SBA-16, as a template through a simple polymerization reaction between ethylenediamine and carbon tetrachloride. The material has been unambiguously characterized by various sophisticated techniques such as XRD, nitrogen adsorption, HRTEM, EELS, XPS, 13C DD-MAS, and FT-IR spectroscopy. The XD result reveals that MCN-2 possesses three-dimensional structure with a possible Im3m space group. The specific surface area and pore volume of MCN-2 are significantly higher as compared to those of the template and MCN-I. Because of the excellent textural characteristic and three-dimensional porous structure, we believe that the MCN-2 could offer great potential for the applications such as catalysis and adsorption.

AB - A novel highly ordered three-dimensional mesoporous carbon-nitride-based hybrid material (MCN-2) with very high surface area, pore volume, and a possible cage type porous structure has been prepared using three-dimensional cage type mesoporous silica, SBA-16, as a template through a simple polymerization reaction between ethylenediamine and carbon tetrachloride. The material has been unambiguously characterized by various sophisticated techniques such as XRD, nitrogen adsorption, HRTEM, EELS, XPS, 13C DD-MAS, and FT-IR spectroscopy. The XD result reveals that MCN-2 possesses three-dimensional structure with a possible Im3m space group. The specific surface area and pore volume of MCN-2 are significantly higher as compared to those of the template and MCN-I. Because of the excellent textural characteristic and three-dimensional porous structure, we believe that the MCN-2 could offer great potential for the applications such as catalysis and adsorption.

UR - https://www.scopus.com/pages/publications/34548336379

U2 - 10.1021/cm070657k

DO - 10.1021/cm070657k

M3 - Article

AN - SCOPUS:34548336379

SN - 0897-4756

VL - 19

SP - 4367

EP - 4372

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 17

ER -

Three-dimensional cage type mesoporous CN-based hybrid material with very high surface area and pore volume

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