Trace element variation in olivine in the Skaergaard intrusion: Petrologic implications

Olivine from the Layered Series (LS), Upper Border Series (UBS), and Marginal Border Series (MBS) of the Skaergaard intrusion was analyzed to examine trace element variations. In general, olivine from all three series shows similar trends in trace elements with differentiation. Ba, Cs, Rb, and Sr, acted as excluded trace elements and the transition elements, Co, Cr, Cu, Ni, Sc, Zn, and V, are included in Skaergaard olivine. Owing to the high D_Ni in olivine, Ni decreases with differentiation in both olivine and the calculated Skaergaard magma. The low concentration of Cr in olivine is attributable to early depletion of Cr by pyroxene crystallization. Decreases in the abundances of V and Co are related to the onset of magnetite crystallization and the separation of immiscible Co-rich sulphide. In general, calculated partition coefficients (D_i) for Skaergaard olivine show similar trends in the LS, UBS, and MBS. Calculated D'_is for Sc, Cr, and Ga in olivine, progressively increase, and D'_is for Zr, Nb, Hf, Cs, Ta, Th, and U progressively decrease, with differentiation. The systematic variation in trace element contents of Skaergaard olivine during differentiation would appear to preclude the possibility of any significant injection of new magma into the chamber during differentiation. The Ni content in Skaergaard olivine systematically decreases with differentiation as would be expected if the intrusion remained a closed system. In fact, no abrupt increases are observed in the abundances of any of the transition metal in olivine during differentiation.