TY - JOUR
T1 - Trans-{1,8-Bis[(R) α- Methyl-benz-yl]-1,3,6,8,10,13-hexa-azacyclo- tetra-deca-ne}dithio-cyanato-nickel(II)
AU - Shin, Jong Won
AU - Min, Kil Sik
PY - 2009
Y1 - 2009
N2 - The title compound, [Ni(NCS)2(C24H38N6)], is a thio-cyanate-coordinated aza-macrocyclic nickel(II) complex. There are two independent mol-ecules in the asymmetric unit and their bond lengths and angles are similar. Both Ni atoms have a tetra-gonally distorted octa-hedral geometry, in which the Ni II ion is coordinated by the four secondary N atoms of the aza-macrocyclic ligand and by two N atoms of the thio-cyanate ions. The average equatorial Ni - N bond lengths are shorter than the average axial Ni - N bond lengths [2.071 (1) and 2.115 (2) Å, respectively]. N - H⋯S hydrogen-bonding inter-actions between a secondary amine N atom and the adjacent thio-cyanate ion leads to a polymeric chain along [100].
AB - The title compound, [Ni(NCS)2(C24H38N6)], is a thio-cyanate-coordinated aza-macrocyclic nickel(II) complex. There are two independent mol-ecules in the asymmetric unit and their bond lengths and angles are similar. Both Ni atoms have a tetra-gonally distorted octa-hedral geometry, in which the Ni II ion is coordinated by the four secondary N atoms of the aza-macrocyclic ligand and by two N atoms of the thio-cyanate ions. The average equatorial Ni - N bond lengths are shorter than the average axial Ni - N bond lengths [2.071 (1) and 2.115 (2) Å, respectively]. N - H⋯S hydrogen-bonding inter-actions between a secondary amine N atom and the adjacent thio-cyanate ion leads to a polymeric chain along [100].
UR - http://www.scopus.com/inward/record.url?scp=60349093408&partnerID=8YFLogxK
U2 - 10.1107/S1600536809002700
DO - 10.1107/S1600536809002700
M3 - Article
AN - SCOPUS:60349093408
SN - 1600-5368
VL - 65
SP - m234
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 2
ER -