Abstract
In the centrosymmetric title compound, [Ni(N3)2(C22H34N6)], the Ni II ion is coordinated by the four secondary N atoms of the macrocyclic ligand in a square-planar fashion with two N atoms of the azide ions in axial positions, resulting in a tetra-gonally distorted octa-hedron. An N - H⋯N hydrogen-bonding inter-action between the secondary amine N atom of the macrocycle and an adjacent azide ion gives rise to a chain structure.
Original language | English |
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Pages (from-to) | m941 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 64 |
Issue number | 7 |
DOIs | |
State | Published - 2008 |