Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation: Synthesis and characterization of [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3] 0.5(BF4)0.5·1.5MeOH·H 2O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]

Kil Sik Min; Arnold L. Rhinegold; Joel S. Miller

doi:10.1021/ja0566984

Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation: Synthesis and characterization of [(TPA)(OH)Fe^IIIOFe^III(OH)(TPA)][Fe(CA)₃] _0.5(BF₄)_0.5·1.5MeOH·H ₂O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]

Kil Sik Min
, Arnold L. Rhinegold
, Joel S. Miller

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

[(TPA)(OH)Fe^IIIOFe^III(OH)(TPA)][Fe(CA)₃]_0.5(BF₄)_0.5·1.5MeOH·H₂O (1) which possesses both the [Fe^III(CA)₃]^3- (CA= chloranilate) and hydroxooxoiron(III) ions has had its structure determined by single-crystal X-ray diffraction. The 2-300 K magnetic susceptibility of 1 provides the magnetic parameters, g = 2.07, J/k_B = -165 K (115 cm^-1), θ = -1 K, and the spin impurity, ρ = 0.05, which indicates a strong antiferromagnetic interaction between iron(III) ions via the oxo anion.

Original language	English
Pages (from-to)	40-41
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	1
DOIs	https://doi.org/10.1021/ja0566984
State	Published - 11 Jan 2006

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Min, K. S., Rhinegold, A. L., & Miller, J. S. (2006). Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation: Synthesis and characterization of [(TPA)(OH)Fe^IIIOFe^III(OH)(TPA)][Fe(CA)₃] _0.5(BF₄)_0.5·1.5MeOH·H ₂O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]. Journal of the American Chemical Society, 128(1), 40-41. https://doi.org/10.1021/ja0566984

Min, Kil Sik ; Rhinegold, Arnold L. ; Miller, Joel S. / Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation : Synthesis and characterization of [(TPA)(OH)Fe^IIIOFe^III(OH)(TPA)][Fe(CA)₃] _0.5(BF₄)_0.5·1.5MeOH·H ₂O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]. In: Journal of the American Chemical Society. 2006 ; Vol. 128, No. 1. pp. 40-41.

@article{825883a83f7f482a90151e8b7d87bd9e,

title = "Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation: Synthesis and characterization of [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3] 0.5(BF4)0.5·1.5MeOH·H 2O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]",

abstract = "[(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3]0.5(BF4)0.5·1.5MeOH·H2O (1) which possesses both the [FeIII(CA)3]3- (CA= chloranilate) and hydroxooxoiron(III) ions has had its structure determined by single-crystal X-ray diffraction. The 2-300 K magnetic susceptibility of 1 provides the magnetic parameters, g = 2.07, J/kB = -165 K (115 cm-1), θ = -1 K, and the spin impurity, ρ = 0.05, which indicates a strong antiferromagnetic interaction between iron(III) ions via the oxo anion.",

author = "Min, \{Kil Sik\} and Rhinegold, \{Arnold L.\} and Miller, \{Joel S.\}",

year = "2006",

month = jan,

day = "11",

doi = "10.1021/ja0566984",

language = "English",

volume = "128",

pages = "40--41",

journal = "Journal of the American Chemical Society",

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publisher = "American Chemical Society",

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Min, KS, Rhinegold, AL & Miller, JS 2006, 'Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation: Synthesis and characterization of [(TPA)(OH)Fe^IIIOFe^III(OH)(TPA)][Fe(CA)₃] _0.5(BF₄)_0.5·1.5MeOH·H ₂O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]', Journal of the American Chemical Society, vol. 128, no. 1, pp. 40-41. https://doi.org/10.1021/ja0566984

Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation: Synthesis and characterization of [(TPA)(OH)Fe^IIIOFe^III(OH)(TPA)][Fe(CA)₃] _0.5(BF₄)_0.5·1.5MeOH·H ₂O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]. / Min, Kil Sik; Rhinegold, Arnold L.; Miller, Joel S.
In: Journal of the American Chemical Society, Vol. 128, No. 1, 11.01.2006, p. 40-41.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Tris(chloranilato)ferrate(III) anionic building block containing the (dihydroxo)oxodiiron(III) dimer cation

T2 - Synthesis and characterization of [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3] 0.5(BF4)0.5·1.5MeOH·H 2O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate]

AU - Min, Kil Sik

AU - Rhinegold, Arnold L.

AU - Miller, Joel S.

PY - 2006/1/11

Y1 - 2006/1/11

N2 - [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3]0.5(BF4)0.5·1.5MeOH·H2O (1) which possesses both the [FeIII(CA)3]3- (CA= chloranilate) and hydroxooxoiron(III) ions has had its structure determined by single-crystal X-ray diffraction. The 2-300 K magnetic susceptibility of 1 provides the magnetic parameters, g = 2.07, J/kB = -165 K (115 cm-1), θ = -1 K, and the spin impurity, ρ = 0.05, which indicates a strong antiferromagnetic interaction between iron(III) ions via the oxo anion.

AB - [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3]0.5(BF4)0.5·1.5MeOH·H2O (1) which possesses both the [FeIII(CA)3]3- (CA= chloranilate) and hydroxooxoiron(III) ions has had its structure determined by single-crystal X-ray diffraction. The 2-300 K magnetic susceptibility of 1 provides the magnetic parameters, g = 2.07, J/kB = -165 K (115 cm-1), θ = -1 K, and the spin impurity, ρ = 0.05, which indicates a strong antiferromagnetic interaction between iron(III) ions via the oxo anion.

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