Weak ferromagnetic ordering of the li+[tcne]•- (tcne = tetracyanoethylene) organic magnet with an interpenetrating diamondoid structure

Jae Hyuk Her; Peter W. Stephens; Royce A. Davidson; Kil Sik Min; Joshua D. Bagnato; Kipp Van Schooten; Christoph Boehme; Joel S. Miller

doi:10.1021/ja410818e

Weak ferromagnetic ordering of the li⁺[tcne]^•- (tcne = tetracyanoethylene) organic magnet with an interpenetrating diamondoid structure

Jae Hyuk Her, Peter W. Stephens, Royce A. Davidson, Kil Sik Min, Joshua D. Bagnato, Kipp Van Schooten, Christoph Boehme, Joel S. Miller

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Li[TCNE] (TCNE = tetracyanoethylene) magnetically orders as a weak ferromagnet (canted antiferromagnet) below 21.0 ± 0.1 K, as observed from the bifurcation of the field-cooled and zero-field-cooled magnetizations, as well as remnant magnetization. The structure, determined ab initio from synchrotron X-ray powder diffraction data, consists of a planar μ₄-[TCNE]^•- bound to four tetrahedral Li ⁺ ions. The structure consists of two interpenetrating diamondoid sublattices, with closest interlattice distances of 3.43 and 3.48 Å. At 5 K this magnetic state is characterized by a coercivity of ∼30 Oe, a remnant magnetization of 10 emu·Oe/mol, and a canting angle of 0.5.

Original language	English
Pages (from-to)	18060-18063
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	48
DOIs	https://doi.org/10.1021/ja410818e
State	Published - 4 Dec 2013

Access to Document

10.1021/ja410818e

Cite this

@article{2cea5bbd16cc4e3482c2705ae90902c1,

title = "Weak ferromagnetic ordering of the li+[tcne]•- (tcne = tetracyanoethylene) organic magnet with an interpenetrating diamondoid structure",

abstract = "Li[TCNE] (TCNE = tetracyanoethylene) magnetically orders as a weak ferromagnet (canted antiferromagnet) below 21.0 ± 0.1 K, as observed from the bifurcation of the field-cooled and zero-field-cooled magnetizations, as well as remnant magnetization. The structure, determined ab initio from synchrotron X-ray powder diffraction data, consists of a planar μ4-[TCNE]•- bound to four tetrahedral Li + ions. The structure consists of two interpenetrating diamondoid sublattices, with closest interlattice distances of 3.43 and 3.48 {\AA}. At 5 K this magnetic state is characterized by a coercivity of ∼30 Oe, a remnant magnetization of 10 emu·Oe/mol, and a canting angle of 0.5.",

author = "Her, {Jae Hyuk} and Stephens, {Peter W.} and Davidson, {Royce A.} and Min, {Kil Sik} and Bagnato, {Joshua D.} and {Van Schooten}, Kipp and Christoph Boehme and Miller, {Joel S.}",

year = "2013",

month = dec,

day = "4",

doi = "10.1021/ja410818e",

language = "English",

volume = "135",

pages = "18060--18063",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "48",

}

TY - JOUR

T1 - Weak ferromagnetic ordering of the li+[tcne]•- (tcne = tetracyanoethylene) organic magnet with an interpenetrating diamondoid structure

AU - Her, Jae Hyuk

AU - Stephens, Peter W.

AU - Davidson, Royce A.

AU - Min, Kil Sik

AU - Bagnato, Joshua D.

AU - Van Schooten, Kipp

AU - Boehme, Christoph

AU - Miller, Joel S.

PY - 2013/12/4

Y1 - 2013/12/4

N2 - Li[TCNE] (TCNE = tetracyanoethylene) magnetically orders as a weak ferromagnet (canted antiferromagnet) below 21.0 ± 0.1 K, as observed from the bifurcation of the field-cooled and zero-field-cooled magnetizations, as well as remnant magnetization. The structure, determined ab initio from synchrotron X-ray powder diffraction data, consists of a planar μ4-[TCNE]•- bound to four tetrahedral Li + ions. The structure consists of two interpenetrating diamondoid sublattices, with closest interlattice distances of 3.43 and 3.48 Å. At 5 K this magnetic state is characterized by a coercivity of ∼30 Oe, a remnant magnetization of 10 emu·Oe/mol, and a canting angle of 0.5.

AB - Li[TCNE] (TCNE = tetracyanoethylene) magnetically orders as a weak ferromagnet (canted antiferromagnet) below 21.0 ± 0.1 K, as observed from the bifurcation of the field-cooled and zero-field-cooled magnetizations, as well as remnant magnetization. The structure, determined ab initio from synchrotron X-ray powder diffraction data, consists of a planar μ4-[TCNE]•- bound to four tetrahedral Li + ions. The structure consists of two interpenetrating diamondoid sublattices, with closest interlattice distances of 3.43 and 3.48 Å. At 5 K this magnetic state is characterized by a coercivity of ∼30 Oe, a remnant magnetization of 10 emu·Oe/mol, and a canting angle of 0.5.

UR - http://www.scopus.com/inward/record.url?scp=84889852748&partnerID=8YFLogxK

U2 - 10.1021/ja410818e

DO - 10.1021/ja410818e

M3 - Article

AN - SCOPUS:84889852748

SN - 0002-7863

VL - 135

SP - 18060

EP - 18063

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 48

ER -

Weak ferromagnetic ordering of the li⁺[tcne]^•- (tcne = tetracyanoethylene) organic magnet with an interpenetrating diamondoid structure

Abstract

Access to Document

Other files and links

Fingerprint

Cite this