X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene

Thanh Tuan Bui; Aude Escande; Christian Philouze; Gianluca Cioci; Sudip Ghosh; Eric Saint-Aman; Jong Min Lim; Jean Claude Moutet; Jonathan L. Sessler; Dongho Kim; Christophe Bucher

doi:10.1142/S1088424612501325

X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene

Thanh Tuan Bui, Aude Escande, Christian Philouze, Gianluca Cioci, Sudip Ghosh, Eric Saint-Aman, Jong Min Lim, Jean Claude Moutet, Jonathan L. Sessler, Dongho Kim, Christophe Bucher

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.

Original language	English
Pages (from-to)	27-35
Number of pages	9
Journal	Journal of Porphyrins and Phthalocyanines
Volume	17
Issue number	1-2
DOIs	https://doi.org/10.1142/S1088424612501325
State	Published - 2013

Keywords

cyclopyrrole
electrochemical synthesis
expanded porphyrin
nonaphyrin
synchrotron radiation

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title = "X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene",

abstract = "A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.",

keywords = "cyclopyrrole, electrochemical synthesis, expanded porphyrin, nonaphyrin, synchrotron radiation",

author = "Bui, {Thanh Tuan} and Aude Escande and Christian Philouze and Gianluca Cioci and Sudip Ghosh and Eric Saint-Aman and Lim, {Jong Min} and Moutet, {Jean Claude} and Sessler, {Jonathan L.} and Dongho Kim and Christophe Bucher",

year = "2013",

doi = "10.1142/S1088424612501325",

language = "English",

volume = "17",

pages = "27--35",

journal = "Journal of Porphyrins and Phthalocyanines",

issn = "1088-4246",

publisher = "World Scientific",

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}

TY - JOUR

T1 - X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene

AU - Bui, Thanh Tuan

AU - Escande, Aude

AU - Philouze, Christian

AU - Cioci, Gianluca

AU - Ghosh, Sudip

AU - Saint-Aman, Eric

AU - Lim, Jong Min

AU - Moutet, Jean Claude

AU - Sessler, Jonathan L.

AU - Kim, Dongho

AU - Bucher, Christophe

PY - 2013

Y1 - 2013

N2 - A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.

AB - A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.

KW - cyclopyrrole

KW - electrochemical synthesis

KW - expanded porphyrin

KW - nonaphyrin

KW - synchrotron radiation

UR - http://www.scopus.com/inward/record.url?scp=84874171759&partnerID=8YFLogxK

U2 - 10.1142/S1088424612501325

DO - 10.1142/S1088424612501325

M3 - Article

AN - SCOPUS:84874171759

SN - 1088-4246

VL - 17

SP - 27

EP - 35

JO - Journal of Porphyrins and Phthalocyanines

JF - Journal of Porphyrins and Phthalocyanines

IS - 1-2

ER -

X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene

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