Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid

Maria N. Timofeeva; Valentina N. Panchenko; Ivan A. Lukoyanov; Sung Hwa Jhung

doi:10.1007/s11144-021-01982-1

Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid

Maria N. Timofeeva
, Valentina N. Panchenko
, Ivan A. Lukoyanov
, Sung Hwa Jhung

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Porous Zr-based metal–organic frameworks (MOF-808 and MOF-808/H₂SO₄, UiO-66 and UiO-66-SO₃H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 °C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order: MOF-808/H₂SO₄ > MOF-808 > UiO-66-SO₃H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H₂SO₄ was found to be the best catalyst, resulting in the formation of N-formylaniline in 96% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H₂SO₄ were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.

Original language	English
Pages (from-to)	355-369
Number of pages	15
Journal	Reaction Kinetics, Mechanisms and Catalysis
Volume	133
Issue number	1
DOIs	https://doi.org/10.1007/s11144-021-01982-1
State	Published - Jun 2021

Keywords

Aniline
Brønsted acidity
Formic acid
Metal–organic framework
N-formylation

Access to Document

10.1007/s11144-021-01982-1

Cite this

@article{0b4df0fa0c5449c29132f845eb7c4c79,

title = "Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid",

abstract = "Porous Zr-based metal–organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 °C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order: MOF-808/H2SO4 > MOF-808 > UiO-66-SO3H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H2SO4 was found to be the best catalyst, resulting in the formation of N-formylaniline in 96\% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H2SO4 were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.",

keywords = "Aniline, Br{\o}nsted acidity, Formic acid, Metal–organic framework, N-formylation",

author = "Timofeeva, \{Maria N.\} and Panchenko, \{Valentina N.\} and Lukoyanov, \{Ivan A.\} and Jhung, \{Sung Hwa\}",

note = "Publisher Copyright: {\textcopyright} 2021, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2021",

month = jun,

doi = "10.1007/s11144-021-01982-1",

language = "English",

volume = "133",

pages = "355--369",

journal = "Reaction Kinetics, Mechanisms and Catalysis",

issn = "1878-5190",

publisher = "Springer Science and Business Media B.V.",

number = "1",

}

TY - JOUR

T1 - Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid

AU - Timofeeva, Maria N.

AU - Panchenko, Valentina N.

AU - Lukoyanov, Ivan A.

AU - Jhung, Sung Hwa

PY - 2021/6

Y1 - 2021/6

N2 - Porous Zr-based metal–organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 °C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order: MOF-808/H2SO4 > MOF-808 > UiO-66-SO3H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H2SO4 was found to be the best catalyst, resulting in the formation of N-formylaniline in 96% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H2SO4 were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.

AB - Porous Zr-based metal–organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 °C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order: MOF-808/H2SO4 > MOF-808 > UiO-66-SO3H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H2SO4 was found to be the best catalyst, resulting in the formation of N-formylaniline in 96% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H2SO4 were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.

KW - Aniline

KW - Brønsted acidity

KW - Formic acid

KW - Metal–organic framework

KW - N-formylation

UR - https://www.scopus.com/pages/publications/85105379436

U2 - 10.1007/s11144-021-01982-1

DO - 10.1007/s11144-021-01982-1

M3 - Article

AN - SCOPUS:85105379436

SN - 1878-5190

VL - 133

SP - 355

EP - 369

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

IS - 1

ER -

Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this